Synthesis of 4-hydroxycoumarin and 3-acetyl-4-hydroxycoumarin in the presence and absence of ultrasonic bath and evaluation of their anticoagulant effects

Firoozi, Sanaz; Salahvarzi, Sabah; Dadgar, Zeynab

doi:10.48309/JMNC.2024.1.4

Document Type : Original Article

Authors

Department of Chemistry, Faculty of Science, Khorramabad Branch, Islamic Azad University, Khorramabad, Iran

https://doi.org/10.48309/JMNC.2024.1.4

Abstract

Biochar is a cost-effective and porous material with high carbon content. It is considered as an effective supporting matrix owing to its high specific surface area and notable ion exchange ability. In this work, a porous biochar support was fabricated from pistachio residues using pyrolysis procedure. Subsequently, various crystalline phases and morphologies of MnO₂ were deposited onto the biochar support through chemical protocols with Mn(Ac)₂, KMnO₄, and MnSO₄ as Mn source. The N₂ adsorption-desorption experiments were employed to characterize the porosities and specific surface areas of the synthesized nanocomposites. It is found that the γ-MnO₂/biochar composite possessed the higher surface area than the δ-MnO₂ and α-MnO₂ samples. The adsorption features of the composite materials in the removement of target dye from aqueous solution were also examined. Based on the experimental results, the γ-MnO₂/biochar sample showed the highest efficiency for removal of target dye. In addition, the experimental data exhibited a good correlation (R² greater than 0.99) with the pseudo-second-order kinetic model, indicating a chemical adsorption approach for dye adsorption.

Graphical Abstract

Keywords

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Journal of Medicinal and Nanomaterials Chemistry

Synthesis of 4-hydroxycoumarin and 3-acetyl-4-hydroxycoumarin in the presence and absence of ultrasonic bath and evaluation of their anticoagulant effects

References

References

Volume 6, Issue 1
January 2024
Pages 31-45

Synthesis of 4-hydroxycoumarin and 3-acetyl-4-hydroxycoumarin in the presence and absence of ultrasonic bath and evaluation of their anticoagulant effects

References

References

Volume 6, Issue 1January 2024Pages 31-45

Volume 6, Issue 1
January 2024
Pages 31-45